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propiolic acid : ウィキペディア英語版
propiolic acid

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Propiolic acid is an unsaturated carboxylic acid. It is a colourless liquid that crystallises to give silky crystals. Near its boiling point, it decomposes. It is soluble in water and possesses an odor like that of acetic acid.
==Preparation==
It is prepared commercially by oxidizing propargyl alcohol at a lead electrode.〔Wilhelm Riemenschneider "Carboxylic Acids, Aliphatic" Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. .〕 It can also be prepared by decarboxylation of acetylenedicarboxylic acid.
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